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Selected Research Projects

1- Feasibility study of granular activated carbon to reduce PFOA and PFOS emissions from municipal wastewater treatment plants (funded by Environment and Climate Change Canada)

  • Investigate efficiency and economic viability of granular activated carbon and biochar for the removal of short- and long-chain PFAS compounds from municipal wastewater treatment plants’ effluents through rapid small-scale column tests.

  • Estimate costs and potential reduction of PFAS loads entering the Great Lakes assuming implementation of GAC filters as a final polishing step in wastewater treatment plants discharging to the Great Lakes.

 

2- Design of efficient carbon-based adsorbents for the removal of organic and inorganic water contaminants (projects funded by U.S. DOE and SRNS)

(i) Activated carbon coated by polysulfide rubber (AC-PSR)

  • Synthesized polysulfide rubber polymer (PSR) and coated that onto granular activated carbon (AC) to produce AC-PSR composite adsorbent

  • Employed FTIR for polymer characterization, and compared morphological and chemical characteristics of AC-PSR against unmodified AC, using TGA, BET, SEM, TEM, EDS, and XPS

  • Compared hexavalent chromium removal efficiencies of AC-PSR and AC, investigated adsorption isotherms, kinetics, and intraparticle diffusion mechanism of Cr(VI) ions

  • Investigated regeneration and reusability of AC-PSR for Cr(VI) removal

(ii) Activated carbon impregnated by zero-valent iron nanoparticles (AC/nZVI)

  • Immobilized zero-valent iron nanoparticles (nZVI) onto activated carbon to produce AC/nZVI composite adsorbent, using a combined annealing and borohydride reduction technique

  • Compared morphological and chemical characteristics of AC/nZVI against AC, using SEM, TEM, EDS, XPS, and TAFEL corrosion test

  • Compared Cr(VI) removal efficiencies of AC/nZVI and AC, investigated adsorption isotherms, kinetics, and intraparticle diffusion mechanism of chromium ions

  • Investigated AC/nZVI regeneration and reusability for Cr(VI) removal

(iii) Biochar modification by heat treatment and nZVI impregnation

  • Modified biochar (BC) by heat treatment to produce hydrophilic biochar (HBC), and impregnated both BC and HBCs by zero-valent iron nanoparticles (producing BC/nZVI and HBC/nZVI composites)

  • Compared morphological and chemical characteristics of various synthesized composites using BET, SEM, TEM, EDS, XPS, FTIR, and sessile drop contact angle

  • Investigated removal efficiency and kinetics of Cr(VI), trichloroethylene (TCE), and p-nitrosodimethylaniline (pNDA) using HBC/nZVI

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3-Immobilization of zero-valent iron nanoparticles onto mesoporous silica (Funded by U.S. DOE)  

  • Immobilized zero-valent iron nanoparticles (nZVI) onto SBA-15 mesoporous silica, producing nZVI/SBA-15 composite, optimized synthesis conditions by characterizing various composites with SEM, EDS, TEM, XPS, and ICP, and by comparing their p-nitrosodimethylaniline (pNDA) removal efficiencies

  • Examined the effects of hydroxyl radical scavengers and DO concentration on pNDA bleaching, and proposed a new pathway for pNDA degradation through reduction

 

4- Treatment of oily wastewaters (Funded by TESLA Gigafactory)

  • First phase: designed a treatment chain consisting of oil skimmer, coagulation, and ultrafiltration for the treatment of synthetic oily wastewater consisted of 20% industrial oil

  • Second phase: hydrophobic/lipophilic biochar column for the separation of industrial oils from water5- Synthesis of a visible-light-driven photocatalyst

  • Synthesized a visible-light activated Z-scheme photocatalyst for water treatment under different synthesis conditions

  • Characterized the catalysts by SEM, TEM, EDS, and XPS

  • Investigated catalyst’s efficiency for the degradation of methylene blue dye under visible light using a solar radiation simulator

  • Investigated the effects of hydroxyl radical scavengers, hole scavengers, and superoxide anion scavengers on the photocatalyst’s degradation efficiency

Department of Civil and Mineral Engineering, University of Toronto,

35 St. George St., Toronto, Ontario, Canada M5S 1A4

Email: soroosh.mortazavian@utoronto.ca

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